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title高性能酸化剤アンモニウムジニトラミドの凝縮相分解反応解析
Other TitleDecomposition of the high-performance oxidizer ammonium dinitramide in condensed phase
Author(jpn)松永, 浩貴; 羽生, 宏人; 三宅, 淳巳
Author(eng)Matsunaga, Hiroki; Habu, Hiroto; Miyake, Atsumi
Author Affiliation(jpn)横浜国立大学大学院環境情報研究院・環境情報学府 : 日本学術振興会特別研究員; 宇宙航空研究開発機構宇宙科学研究所宇宙飛翔工学研究系(JAXA)(ISAS); 横浜国立大学大学院環境情報学府
Author Affiliation(eng)Graduate School of Environment and Information Sciences, Yokohama National University : Research Fellow of Japan Society for the Promotion of Science; Division for Space Flight Systems, Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency (JAXA)(ISAS); Graduate School of Environment and Information Sciences, Yokohama National University
Issue Date2014-03-31
Publisher宇宙航空研究開発機構(JAXA)
Japan Aerospace Exploration Agency (JAXA)
Publication title宇宙航空研究開発機構研究開発報告: 高エネルギー物質研究会: 平成25年度研究成果報告書
JAXA Research and Development Report: Collaborative Research Activity on Energetic Materials Research Report FY2013
VolumeJAXA-RR-13-009
Start page13
End page22
Publication date2014-03-31
Languagejpn
eng
Abstractアンモニウムジニトラミド(ADN)は,高酸素バランス,高エネルギー,ハロゲンフリーであることから,固体ロケット推進薬の新しい高性能酸化剤として実用が期待されている物質である.固体ロケット推進薬での実用に向け重要な情報の一つに化学的安定性が挙げられる.本研究ではADNの熱分解機構に着目し,示差走査熱量測定 (DSC)とラマン分光分析を組み合わせ,定速昇温時の発熱挙動と凝縮相中の分解生成物の同時測定を行った.ADNの熱分解は多段階であり,分解初期では,ADNの硝酸アンモニウム(AN)への分解が主反応であることが明らかとなった.さらに昇温を続けるとADNの分解のほかANが寄与する反応が進行することがわかった。
Ammonium dinitramide (ADN) is the promising new energetic oxidizers for solid propellant because of its high oxygen balance and high energy content, and halogen-free combustion products. For practical use of ADN, one of the important characteristics is chemical stability. This study focused on thermal decomposition mechanism of ADN. Its exothermal behavior and decomposition products in condensed phase during constant rate heating were measured simultaneously with differential scanning calorimetry (DSC) and Raman spectrometry. These analyses showed that the decomposition of ADN proceeded via multiple stages. It was found that one of the main reactions at beginning of ADN decomposition is generation of ammonium nitrate (AN). With more heating, not only ADN decomposition but also the reactions involving AN proceeded.
Description形態: カラー図版あり
Physical characteristics: Original contains color illustrations
Keywordsammonium dinitramide; solid propellant; thermal decomposition mechanism
Document TypeTechnical Report
JAXA Category研究開発報告
NASA Subject CategoryPropellants and Fuels
ISSN1349-1113
NCIDAA1192675X
SHI-NOAA0062089002
Report NoJAXA-RR-13-009
URIhttps://repository.exst.jaxa.jp/dspace/handle/a-is/21786


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