| タイトル | リモネンジオールと炭酸ジメチルとの反応挙動の評価 |
| その他のタイトル | Study on the reaction behavior of limonenediols and dimethyl carbonate |
| 参考URL | http://doi.org/10.34411/00032049 |
| 著者（日） | 森川, 浩; 原澤, 慎樹; 藤村, 陽; 本九町, 卓 |
| 著者（英） | Morikawa, Hiroshi; Harasawa, Yoshiki; Fujimura, Yo; Motokucho, Suguru |
| 著者所属（日） | 神奈川工科大学; 神奈川工科大学; 神奈川工科大学; 長崎大学 |
| 著者所属（英） | Kanagawa Institute of Technology; Kanagawa Institute of Technology; Kanagawa Institute of Technology; Nagasaki University |
| 発行日 | 2021-03-01 |
| 発行機関など | 神奈川工科大学
Kanagawa Institute of Technology |
| 刊行物名 | 神奈川工科大学研究報告: B理工学編
Research Reports of Kanagawa Institute of Technology: Part B. Science and Technology |
| 号 | 45 |
| 開始ページ | 67 |
| 終了ページ | 70 |
| 刊行年月日 | 2021-03-01 |
| 言語 | jpn
eng |
| 抄録 | To develop biomass-derived chemicals, reaction behavior of dimethyl carbonate (DMC) with four types of limonene-1,2-diol (LMdiol) was studied in the presence of catalysts such as 4-dimethylaminopyridine. Each of the reaction was carried out without any addition of organic solvents at 90 C for 6-48 hours, in which the feed molar ratio of LMdiol : DMC : catalyst was fixed to 1.0 : 2.0 : 0.2. In all cases, the reactions produced no polymeric products, poly(limonene carbonate). The 1H NMR spectroscopic analysis revealed that the reaction products were dependent on the stereochemical configuration at two hydroxy groups of starting LMdiols, resulting in formation of the corresponding fused five-membered cyclic carbonates, monoalcohol-monocarbonate, and trans-limonene oxide. |
| 内容記述 | 形態: カラー図版あり
Physical characteristics: Original contains color illustrations |
| キーワード | Biomass; Limonene; Diol; Carbonate; Reaction behaviour |
| 資料種別 | Departmental Bulletin Paper |
| NASA分類 | Inorganic, Organic and Physical Chemistry |
| ISSN | 2188-2878 |
| NCID | AA12669200 |
| SHI-NO | AA2140231000 |
| URI | https://repository.exst.jaxa.jp/dspace/handle/a-is/1045584 |
