AIREX: Time-resolved X-ray Tracking of Expansion and Compression Dynamics in Supersaturating Ion-Networks

タイトル	Time-resolved X-ray Tracking of Expansion and Compression Dynamics in Supersaturating Ion-Networks
DOI	https://doi.org/10.1038/srep17647
本文（外部サイト）	https://ir.library.osaka-u.ac.jp/repo/ouka/all/71269/SR_5_17647.pdf
著者（英）	Matsushita, Y.; Sekiguchi, H.; Ichiyanagi, K.; Ohta, N.; Ikezaki, K.; Goto, Y.; Sasaki, Y.C.
発行日	2015-12
発行機関など	Springer Nature
刊行物名	Scientific Reports
巻	5
開始ページ	17647
言語	eng
内容記述	Y. Matsushita, H. Sekiguchi, K. Ichiyanagi, N. Ohta, K. Ikezaki, Y. Goto & Y. C. Sasaki "Time-resolved X-ray Tracking of Expansion and Compression Dynamics in Supersaturating Ion-Networks", Scientific Reports, volume 5, Article number: 17647, Springer Nature, 2015 Supersaturation of a solution system is a metastable state containing more solute than can be normally solubilized. Moreover, this condition is thermodynamically important for a system undergoing a phase transition. This state plays critical roles in deposition morphology in inorganic, organic, polymer and protein solution systems. In particular, microscopic solution states under supersaturated conditions have recently received much attention. In this report, we observed the dynamic motion of individual ion-network domains (INDs) in a supersaturated sodium acetate trihydrate solution (6.4 M) by using microsecond time-resolved and high accuracy (picometre scale) X-ray observations (diffracted X-ray tracking; DXT). We found that there are femto-Newton (fN) anisotropic force fields in INDs that correspond to an Angstrom-scale relaxation process (continuous expansion and compression) of the INDs at 25 μs time scale. The observed anisotropic force-field (femto-Newton) from DXT can lead to new explanations of how material crystallization is triggered. This discovery could also influence the interpretation of supercooling, bio-polymer and protein aggregation processes, and supersaturated systems of many other materials.
権利	© 2015 The Author(s). This article is licensed under a Creative Commons Attribution 4.0 International License.
URI	https://repository.exst.jaxa.jp/dspace/handle/a-is/1234696