タイトル | Crystal chemical and quantum chemical studies of Ba(Sr)-Nb oxide compounds |
本文(外部サイト) | http://hdl.handle.net/2060/19900018542 |
著者(英) | Liechtenstein, A. I.; Zubkov, V. G.; Pereliaev, V. A.; Gubanov, V. A.; Turzhevsky, S. A. |
著者所属(英) | Academy of Sciences (USSR) |
発行日 | 1990-04-01 |
言語 | eng |
内容記述 | The information available on the BaO(SrO)-NbO-NbO2 system with the niobium atom in the lower oxidation degree is very limited. Very few compounds have been found previously in this system. They are BaNbO3, SrxNbO3(0,7=x=1), Ba2Nb2O9, SrNb8O14; and some suggestions on the BaNb8O14 existence have been made also. At the same time Nb-based oxide compounds could be quite interesting in the search of new noncopper high T(sub c) superconductors Researchers studied Ba(Sr) NbxO2x-2 and Ba2(Sr2)-NbxO2x-1 compositions in the phase diagram of BaO(SrO)-NbO-NbO2 system. The synthesis of the materials was carried out in vacuum at the temperatures of 1000 to 1500 C. Barium carbonate and niobium pentoxide were used as initial components. X-ray analysis was carried out. |
NASA分類 | SOLID-STATE PHYSICS |
レポートNO | 90N27858 |
権利 | No Copyright |
URI | https://repository.exst.jaxa.jp/dspace/handle/a-is/136599 |
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