| タイトル | A flash photolysis-resonance fluorescence study of the formation of O(D-1) in the photolysis of water and reaction of O(D-1) with H2, Ar and He |
| 本文（外部サイト） | http://hdl.handle.net/2060/19750002979 |
| 著者（英） | Klemm, R. B.; Stief, L. J.; Payne, W. A. |
| 著者所属（英） | NASA Goddard Space Flight Center |
| 発行日 | 1974-11-01 |
| 言語 | eng |
| 内容記述 | The relative importance of two primary processes in the photolyis of water: (1) H2O + h (nu) yields H + OH, and (2) H2O + h (nu) yields H2 + OD-1 were determined in a direct manner by time resolved detection (via resonance fluorescence) of H and O formed in processes 1 and 2 respectively. The initially formed OD-1 was deactivated to ground state OP-3 prior to detection via resonance fluorescence. The relative quantum yields for processes 1 and 2 are 0.89 and 0.11 for the wavelength interval 105 to 145nm and = to or greater than 0.99, and = to or less than 0.01 for the wavelength interval 145 to 185nm. Rate constants at 300 K for the reactions OD-1 + H2, + Ar, and + He are presented. |
| NASA分類 | INORGANIC AND PHYSICAL CHEMISTRY |
| レポートNO | 75N11051
NASA-TM-X-70784
X-691-74-320 |
| 権利 | No Copyright |
| URI | https://repository.exst.jaxa.jp/dspace/handle/a-is/192212 |
