| タイトル | Aligned Single Wall Carbon Nanotube Polymer Composites Using an Electric Field |
| 本文（外部サイト） | http://hdl.handle.net/2060/20080015451 |
| 著者（英） | Wiklinson, John; Park, Cheol; Wise, Kristopher E.; Harrison, Joycelyn S.; Banda, Sumanth; Ounaies, Zoubeida; Sauti, Godfrey; Lillehei, Peter T. |
| 著者所属（英） | NASA Langley Research Center; National Inst. of Aerospace |
| 発行日 | 2005-01-01 |
| 言語 | eng |
| 内容記述 | While high shear alignment has been shown to improve the mechanical properties of single wall carbon nanotubes (SWNT)-polymer composites, it is difficult to control and often results in degradation of the electrical and dielectric properties of the composite. Here, we report a novel method to actively align SWNTs in a polymer matrix, which allows for control over the degree of alignment of SWNTs without the side effects of shear alignment. In this process, SWNTs are aligned via field-induced dipolar interactions among the nanotubes under an AC electric field in a liquid matrix followed by immobilization by photopolymerization while maintaining the electric field. Alignment of SWNTs was controlled as a function of magnitude, frequency, and application time of the applied electric field. The degree of SWNT alignment was assessed using optical microscopy and polarized Raman spectroscopy and the morphology of the aligned nanocomposites was investigated by high resolution scanning electron microscopy. The structure of the field induced aligned SWNTs is intrinsically different from that of shear aligned SWNTs. In the present work, SWNTs are not only aligned along the field, but also migrate laterally to form thick, aligned SWNT percolative columns between the electrodes. The actively aligned SWNTs amplify the electrical and dielectric properties in addition to improving the mechanical properties of the composite. All of these properties of the aligned nanocomposites exhibited anisotropic characteristics, which were controllable by tuning the applied field conditions. |
| NASA分類 | Nonmetallic Materials |
| 権利 | Copyright, Distribution as joint owner in the copyright |
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