| タイトル | Composite Electrolytes for Lithium Batteries: Ionic Liquids in APTES Crosslinked Polymers |
| 本文（外部サイト） | http://hdl.handle.net/2060/20070010743 |
| 著者（英） | Bennett, William R.; Meador, Mary Ann B.; Tigelaar, Dean M. |
| 著者所属（英） | NASA Glenn Research Center |
| 発行日 | 2007-01-01 |
| 言語 | eng |
| 内容記述 | Solvent free polymer electrolytes were made consisting of Li(+) and pyrrolidinium salts of trifluoromethanesulfonimide added to a series of hyperbranched poly(ethylene oxide)s (PEO). The polymers were connected by triazine linkages and crosslinked by a sol-gel process to provide mechanical strength. The connecting PEO groups were varied to help understand the effects of polymer structure on electrolyte conductivity in the presence of ionic liquids. Polymers were also made that contain poly(dimethylsiloxane) groups, which provide increased flexibility without interacting with lithium ions. When large amounts of ionic liquid are added, there is little dependence of conductivity on the polymer structure. However, when smaller amounts of ionic liquid are added, the inherent conductivity of the polymer becomes a factor. These electrolytes are more conductive than those made with high molecular weight PEO imbibed with ionic liquids at ambient temperatures, due to the amorphous nature of the polymer. |
| NASA分類 | Inorganic, Organic and Physical Chemistry |
| 権利 | Copyright, Distribution as joint owner in the copyright |
| URI | https://repository.exst.jaxa.jp/dspace/handle/a-is/258845 |
