タイトル | Optimization of the First and Second Hyperpolarizabilities of Organic Dyes (abstract) |
著者(英) | Tiemann, B. G.; Marder, S. R.; Pierce, B. M.; Cheng, L-T.; Friedli, A. C.; Bourhill, G.; Perry, J. W.; Gorman, C. B.; Bredas, J-L.; Meyers, F.; Skindhoj, J. |
発行日 | 1993-10-06 |
言語 | eng |
内容記述 | We have been attempting to correlate hyperpolarizabilities with bond-length alteration (BLA), which is defined as the difference in the average length between adjacent carbon-carbon bonds in a polymethine [(CH)(sub n)] Polyenes have alternating double and single bonds (bond length equal to 1.34 Sand 1.45 U respectively), and thus show a high degree of bond-length alteration (BLA = -0.11 u. |
権利 | Copyright |
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