| タイトル | A Liquid-Liquid Transition in an Undercooled Ti-Zr-Ni Liquid |
| 著者（英） | Kelton, K. F.; Hyers, R. W.; Lee, G. W.; Gangopadhyay, A. K.; Rogers, J. R.; Rathz, T. J. |
| 著者所属（英） | NASA Marshall Space Flight Center |
| 発行日 | 2003-01-01 |
| 言語 | eng |
| 内容記述 | If crystallization can be avoided, liquids enter a metastable (undercooled) state below their equilibrium liquidus temperatures, TI, finally freezing into a glass below a characteristic temperature called the glass transition temperature, T,. In rare cases, the undercooled liquid may undergo a liquid-liquid phase transition (liquid polymorphism) before entering the glassy state. This has been suggested from experimental studies of HzO and Si4. Such phase transitions have been predicted in some stable liquids, i.e. above TI at atmospheric pressure, for Si02 and BeF;, but these have not been verified experimentally. They have been observed in liquids of P7, Sis and C9, but only under high pressure. All of these transitions are driven by an anomalous density change, i.e. change in local structure, with temperature or pressure. In this letter we present the first experimental evidence for a phase transition in a low viscosity liquid that is not driven by an anomalous density change, but by an approach to a constant configuration state. A maximum in the specific heat at constant pressure, similar to what is normally observed near T,, is reported here for undercooled low viscosity liquids of quasicrystal- forming Ti-Zr-Ni alloys. that includes cooperativity, by incorporating a temperature dependent excitation energy fits the data well, signaling a phase transition. |
| NASA分類 | Metals and Metallic Materials |
| 権利 | Copyright |
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