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タイトルTemperature dependence of the ClONO2 UV absorption spectrum
著者(英)Burkholder, James B.; Talukdar, Ranajit K.; Ravishankara, A. R.
著者所属(英)NASA Headquarters
発行日1994-04-01
言語eng
内容記述The temperature dependence of the ClONO2 absorption spectrum has been measured between 220 and 298 K and between 195 and 430 nm using a diode array spectrometer. The absorption cross sections were determined using both: (1) absolute pressure measurements at 296 K and (2) measurements at various temperatures relative to 296 K using a dual absorption cell arrangement. The temperature dependence of the ClONO2 absorption spectrum shows very broad structure. The amplitude of the temperature dependence relative to that at 296 K is weak at short wavelengths, less than 2% at 215 nm and 220 K, but significant at the wavelengths important in the stratosphere, about 30% at 325 nm and 220 K. Our ClONO2 absorption cross section data are in good general agreement with the previous measurements of Molina and Molina (1979).
NASA分類METEOROLOGY AND CLIMATOLOGY
レポートNO95A67050
権利Copyright


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