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タイトルVisible photoluminescence of porous Si(1-x)Ge(x) obtained by stain etching
著者(英)Vasquez, R. P.; Ksendzov, A.; Pike, W. T.; George, T.; Fathauer, R. W.; Taylor, A. P.
著者所属(英)Jet Propulsion Lab., California Inst. of Tech.
発行日1993-07-12
言語eng
内容記述We have investigated visible photoluminescence (PL) from thin porous Si(1-x)Ge(x) alloy layers prepared by stain etching of molecular-beam-epitaxy-grown material. Seven samples with nominal Ge fraction x varying from 0.04 to 0.41 were studied at room temperature and 80 K. Samples of bulk stain etched Si and Ge were also investigated. The composition of the porous material was determined using X-ray photoemission spectroscopy and Rutherford backscattering techniques to be considerably more Ge-rich than the starting epitaxial layers. While the luminescence intensity drops significantly with the increasing Ge fraction, we observe no significant variation in the PL wavelength at room temperature. This is clearly in contradiction to the popular model based on quantum confinement in crystalline silicon which predicts that the PL energy should follow the bandgap variation of the starting material. However, our data are consistent with small active units containing only a few Si atoms that are responsible for the light emission. Such units are present in many compounds proposed in the literature as the cause of the visible PL in porous Si.
NASA分類SOLID-STATE PHYSICS
レポートNO93A50439
権利Copyright
URIhttps://repository.exst.jaxa.jp/dspace/handle/a-is/314985


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