タイトル | Infrared laser spectroscopy of jet-cooled carbon clusters - The bending dynamics of linear C9 |
著者(英) | Van Orden, A.; Hwang, H. J.; Kuo, E. W.; Saykally, R. J. |
著者所属(英) | NASA Headquarters |
発行日 | 1993-05-01 |
言語 | eng |
内容記述 | We report improved measurements for the nu6 antisymmetric stretch fundamental and observation of the (nu6 + nu15) - nu15 and (nu6 + 2nu15) - 2nu15 hot bands of the linear C9 carbon cluster by direct absorption diode laser spectroscopy of a supersonic carbon cluster beam. Analysis of these bands characterizes C9 as a semirigid molecule with a bending potential similar to that of C5 and further evidences the alternation in degree of rigidity of linear carbon clusters with the g-u symmetry of the HOMO. |
NASA分類 | ATOMIC AND MOLECULAR PHYSICS |
レポートNO | 93A40229 |
権利 | Copyright |
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