| タイトル | Interaction of monovalent ions with the water liquid-vapor interface - A molecular dynamics study |
| 著者（英） | Wilson, Michael A.; Pohorille, Andrew |
| 著者所属（英） | California Univ.|NASA Ames Research Center |
| 発行日 | 1991-10-15 |
| 言語 | eng |
| 内容記述 | Results of molecular dynamics calculations are presented for a series of ions at infinite dilution near the water liquid-vapor interface. The free energies of ion transfer from the bulk to the interface are discussed, as are the accompanying changes of water structure at the surface and ion mobilities as a function of their proximity to the interface. It is shown that simple dielectric models do not provide an accurate description of ions at the water surface. The results of the study should be useful in the development of better models incorporating the shape and molecular structure of the interface. |
| NASA分類 | INORGANIC AND PHYSICAL CHEMISTRY |
| レポートNO | 91A56092 |
| 権利 | Copyright |
| URI | https://repository.exst.jaxa.jp/dspace/handle/a-is/345107 |
