| タイトル | Stratospheric photochemical studies with Atmospheric Trace Molecule Spectroscopy (ATMOS) measurements |
| 著者（英） | Callis, Linwood B.; Natarajan, Murali |
| 著者所属（英） | ST Systems Corp.|NASA Langley Research Center |
| 発行日 | 1991-05-20 |
| 言語 | eng |
| 内容記述 | The photochemical partitioning of stratospheric odd chlorine and odd nitrogen is examined utilizing diurnal model calculations and data from the ATMOS experiment. This experiment, conducted during April-May 1985, employed a solar occultation method to obtain vertical profiles of temperature and various other trace constituents at 30 deg N and 48 deg S latitudes. The ATMOS data set confirms the presence of N2O5 in the stratosphere; however, the observed mixing ratios at sunset are more than a factor of 2 less than the calculated values. It is shown that the conversion of N2O5 into HNO3 could take place in the presence of aerosol surfaces quickly enough to affect the N2O5 mixing ratio below 30 km. Inclusion of the heterogeneous reaction brings the calculated N2O5 profile below 30 km into closer agreement with the ATMOS data. |
| NASA分類 | GEOPHYSICS |
| レポートNO | 91A38305 |
| 権利 | Copyright |
| URI | https://repository.exst.jaxa.jp/dspace/handle/a-is/348043 |
