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タイトルTropospheric OH and the lifetimes of hydrochlorofluorocarbons
著者(英)Prather, Michael; Spivakovsky, Clarisa M.
著者所属(英)Harvard Univ.|NASA Goddard Inst. for Space Studies
発行日1990-10-20
言語eng
内容記述Hydrochlorofluorocarbons (HCFCs) may be used as alternatives for the chlorofluorocarbons (CFCs). Lifetimes for the HCFCs are predicted here in two ways: integrating their loss with a global model and scaling to another compound with a better known lifetime. Both approaches are shown to yield similar results. Three-dimensional fields of modeled tropospheric OH concentrations are used to calculate lifetimes against destruction by OH for the HCFCs and other hydrogenated halocarbons. The lifetimes of various hydro-halocarbons are shown to be insensitive to possible spatial variations and seasonal cycles. It is possible to scale the HCFC lifetimes to that of methyl chloroform or methane by using a ratio of the rate coefficients for reaction with OH at an appropriate temperature, about 277 K.
NASA分類ENVIRONMENT POLLUTION
レポートNO91A13135
権利Copyright
URIhttps://repository.exst.jaxa.jp/dspace/handle/a-is/352075


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