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タイトルAtmospheric peroxyacetyl nitrate measurements over the Brazilian Amazon Basin during the wet season - Relationships with nitrogen oxides and ozone
著者(英)Singh, H. B.; O'Hara, D.; Torres, A. L.; Gregory, G. L.; Salas, L.; Herlth, D.; Sachse, G. W.
著者所属(英)San Jose State Univ.|NASA Wallops Flight Facility|SRI International Corp.|NASA Langley Research Center|NASA Ames Research Center
発行日1990-09-20
言語eng
内容記述An analysis is presented on the distribution and variability of PAN as well as its relationship with measured chemical and meteorological parameters. The chemicals of most interest for which measurements were available are PAN, NO(x), O3, CO, and C2Cl4. PAN was measured by the electron capture gas chromatographic technique, and the technique for calibrations and measurements are detailed. Data show that significant concentrations of PAN (5-125 ppt) are present during the wet season and this PAN is 1-5 times more abundant than NO(x). PAN levels at different atmospheric locations are discussed, and it is noted that PAN shows evidence of a possible latitudinal gradient in the free troposphere, with values falling rapidly from the northern midlatitudes toward the equator. High correlations between O3 and PAN levels suggest that nonmethane hydrocarbons may contribute significantly to high O3 in the free troposphere. Evidence indicates that virtually all of the NO(x) above 4 km could result from PAN decomposition.
NASA分類GEOPHYSICS
レポートNO90A52120
権利Copyright
URIhttps://repository.exst.jaxa.jp/dspace/handle/a-is/353556


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