タイトル | Comment on linewidths and shifts in the Stokes-Raman Q branch of D2 in He |
著者(英) | Blackmore, Robert; Green, Sheldon; Monchick, Louis |
著者所属(英) | NASA Goddard Inst. for Space Studies|Johns Hopkins Univ.|International Business Machines Corp. |
発行日 | 1989-07-01 |
言語 | eng |
内容記述 | Collision-induced widths and shifts for Raman Q-branch transitions of D2 in He were calculated from S matrices obtained with converged close coupling scattering calculations on an accurate theoretical interaction potential. Results agree well with experimental values. Discrepancies between experimental line shifts and theoretical values from an earlier study (Blackmore et al., 1988) are traced to a computational error in that work. The effects of vibrational inelasticity and of centrifugal distortion on energy levels and on potential matrix elements, all of which were ignored in the earlier study, are explicitly considered here and found to be small. |
NASA分類 | ATOMIC AND MOLECULAR PHYSICS |
レポートNO | 89A44408 |
権利 | Copyright |
URI | https://repository.exst.jaxa.jp/dspace/handle/a-is/362692 |