タイトル | Kinetics of the reactions of SH radicals with NO2 and O2 |
著者(英) | Molina, M. J.; Stachnik, R. A. |
著者所属(英) | Jet Propulsion Lab., California Inst. of Tech. |
発行日 | 1987-01-01 |
言語 | eng |
内容記述 | The SH + NO2 reaction rate constant was measured by monitoring SH concentrations with long-path optical absorption at 324 nm in a laser photolysis system. At 298 K, the rate constant was found to be (4.8 + or - 1.0) x 10 to the -11th cu cm/molecule per sec. An upper limit of 4 x 10 to the -19th cu cm/molecule per sec was inferred for the SH + O2 reaction, indicating that the atmospheric oxidation of the SH radical may occur via reaction with species such as NO2 and O3. |
NASA分類 | INORGANIC AND PHYSICAL CHEMISTRY |
レポートNO | 88A20317 |
権利 | Copyright |
URI | https://repository.exst.jaxa.jp/dspace/handle/a-is/373482 |