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タイトルC-13 nuclear magnetic resonance in graphite intercalation compounds
著者(英)Tsang, T.; Resing, H. A.
著者所属(英)Howard Univ.|Naval Research Lab.
発行日1985-01-01
言語eng
内容記述The C-13 NMR chemical shifts of graphite intercalation compounds have been calculated. For acceptor types, the shifts come mainly from the paramagnetic (Ramsey) intra-atomic terms. They are related to the gross features of the two-dimensional band structures. The calculated anisotropy is about - 140 ppm and is independent of the finer details such as charge transfer. For donor types, the carbon 2p pi orbitals are spin-polarized because of mixing with metal-conduction electrons, thus there is an additional dipolar contribution which may be correlated with the electronic specific heat. The general agreement with experimental data is satisfactory.
NASA分類SOLID-STATE PHYSICS
レポートNO85A32555
権利Copyright
URIhttps://repository.exst.jaxa.jp/dspace/handle/a-is/391780


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