| タイトル | Rate constant for the reaction of hydroxyl radical with formaldehyde over the temperature range 228-362 K |
| 著者（英） | Michael, J. V.; Stief, L. J.; Nava, D. F.; Payne, W. A. |
| 著者所属（英） | NASA Goddard Space Flight Center|Catholic Univ. of America |
| 発行日 | 1980-09-01 |
| 言語 | eng |
| 内容記述 | Absolute rate constants for the reaction OH + H2CO have been measured over the temperature range 228-362 K using the flash photolysis-resonance fluorescence technique. The results were independent of variations in forbidden H2CO, total pressure of forbidden Ar and flash intensity (i.e., initial forbidden OH). The rate constant was found to be invariant with temperature in this range, the best representation being k1 = (1.05 + or - 0.11) x 10 to the -11th cu cm/molecule sec where the error is two standard deviations. This result is compared with previous absolute and relative determinations of k1. The reaction is also discussed from a theoretical point of view. |
| NASA分類 | CHEMISTRY AND MATERIALS (GENERAL) |
| レポートNO | 80A50147 |
| 権利 | Copyright |
| URI | https://repository.exst.jaxa.jp/dspace/handle/a-is/420382 |
