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タイトルRotational excitation of symmetric top molecules by collisions with atoms. II - Infinite order sudden approximation
著者(英)Green, S.
著者所属(英)Columbia Univ.|Houston Univ.|NASA Goddard Inst. for Space Studies
発行日1979-01-15
言語eng
内容記述The infinite order sudden (IOS) approximation is extended to rotational excitation of symmetric tops by collisions with atoms. After development of a formalism for 'primitive' or 'one-ended' tops, proper parity-adapted linear combinations describing real rotors are considered and modifications needed for asymmetric rigid rotors are noted. The generalized spectroscopic relaxation cross sections are discussed. IOS calculations for NH3-He and H2CO-He are performed and compared with more accurate calculations, and the IOS approximation is found to provide a reasonably accurate description.
NASA分類ATOMIC AND MOLECULAR PHYSICS
レポートNO79A23016
権利Copyright
URIhttps://repository.exst.jaxa.jp/dspace/handle/a-is/428497


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