| タイトル | Theoretical study of the photodissociation of HOCl |
| 著者（英） | Langhoff, S. R.; Jaffe, R. L. |
| 著者所属（英） | NASA Ames Research Center |
| 発行日 | 1978-02-15 |
| 言語 | eng |
| 内容記述 | A study of the UV photodissociation of hypochlorous acid is conducted on the basis of ab initio SCF-Cl calculations. These calculations show that HOCl has only a single peak in the UV photoabsorption spectrum at 220 nm. This result implies that HOCl would have a long lifetime for photodissociation if it were to be formed in the stratosphere. The photodissociation products of HOCl have been identified as Cl+OH, based on an examination of the topographies of the excited electronic state potential energy surfaces. The results of this study indicate that HOCl could be a significant reservoir for stratospheric chlorine. |
| NASA分類 | INORGANIC AND PHYSICAL CHEMISTRY |
| レポートNO | 79A13057 |
| 権利 | Copyright |
| URI | https://repository.exst.jaxa.jp/dspace/handle/a-is/429584 |
