| タイトル | The rate constant for the reaction of O/3P/ atoms with ClONO2 |
| 著者(英) | Spencer, J. E.; Molina, L. T.; Molina, M. J. |
| 著者所属(英) | California Univ. |
| 発行日 | 1977-01-01 |
| 言語 | eng |
| 内容記述 | Experiments were conducted in a conventional fast flow apparatus to study the rate constant and the activation energy for the reaction O(3P) + ClONO2. The air-afterglow technique was used for the detection of oxygen atoms under pseudo first order conditions. A value of (3.4 plus or minus 0.6) x 10 to the -12th exp/(-840 plus or minus 60)T/cu cm/molecule/s was obtained for the rate constant. The observed rate is sufficiently slow so that oxygen atom attack is of minor importance in the stratosphere compared to photolysis. |
| NASA分類 | INORGANIC AND PHYSICAL CHEMISTRY |
| レポートNO | 77A18325 |
| 権利 | Copyright |
| URI | https://repository.exst.jaxa.jp/dspace/handle/a-is/439613 |