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タイトルAdsorption of oxygen on W/100/ - Adsorption kinetics and structure
著者(英)Poppa, H.; Bauer, E.; Viswanath, Y.
著者所属(英)Missouri Univ.|Technische Univ.|NASA Ames Research Center
発行日1976-08-01
言語eng
内容記述The adsorption of oxygen on W(100) single-crystal surfaces is studied by Auger electron spectroscopy (AES), flash desorption, low-energy electron diffraction (LEED), and retarding-field work-function measurements. The AES results reveal stepwise changes in the sticking coefficients in the coverage range 0 to 1 and activated adsorption at higher coverages. Upon room-temperature adsorption, a series of complex LEED patterns is observed. In layers adsorbed at 1050 K and cooled to room temperature, the p(2 x 1) structure is the first ordered structure observed. This structure shows a reversible order-disorder transition between 700 and 1000 K and is characterized by a work function which is lower than that of the clean surface. Heating room-temperature adsorbates changes their structure irreversibly. At temperatures below 750 K, some new structures are observed.
NASA分類INORGANIC AND PHYSICAL CHEMISTRY
レポートNO77A10533
権利Copyright
URIhttps://repository.exst.jaxa.jp/dspace/handle/a-is/440483


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