| タイトル | Organic solvents, electrolytes, and lithium ion cells with good low temperature performance |
| 本文（外部サイト） | http://hdl.handle.net/2060/20080004940 |
| 著者（英） | Huang, Chen-Kuo; Smart, Marshall C.; Bugga, Ratnakumar V.; Surampudi, Subbarao |
| 著者所属（英） | California Inst. of Tech. |
| 発行日 | 2002-12-10 |
| 言語 | eng |
| 内容記述 | Multi-component organic solvent systems, electrolytes and electrochemical cells characterized by good low temperature performance are provided. In one embodiment, an improved organic solvent system contains a ternary mixture of ethylene carbonate, dimethyl carbonate and diethyl carbonate. In other embodiments, quaternary systems include a fourth component, i.e, an aliphatic ester, an asymmetric alkyl carbonate or a compound of the formula LiOX, where X is R, COOR, or COR, where R is alkyl or fluoroalkyl. Electrolytes based on such organic solvent systems are also provided and contain therein a lithium salt of high ionic mobility, such as LiPF.sub.6. Reversible electrochemical cells, particularly lithium ion cells, are constructed with the improved electrolytes, and preferably include a carbonaceous anode, an insertion type cathode, and an electrolyte interspersed therebetween. |
| NASA分類 | Inorganic, Organic and Physical Chemistry |
| 権利 | No Copyright |
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