| タイトル | Synthesis and CV Studies of Dithiol-terminated Metal Terpyridine Complexes |
| 著者（英） | Fan, Wendy; Ng, Hou-Tee; Han, Jie; Asano, Sylvia; Meyyappan, M. |
| 著者所属（英） | NASA Ames Research Center |
| 発行日 | 2003-01-01 |
| 言語 | eng |
| 内容記述 | Transition metal coordination complexes possess unique electronic structures that should be a good model for studying electronic transport behavior at a molecular level. The discrete, multiple redox states, low redox potential and the superb ability to establish contact with other molecular and electronic components by coordination chemistry have made this a subject of investigation for their possible application as active electronic components in molecular devices. We present the synthesis and electrochemical characterization of 4'-thioacetylphenyl-2'2:6',2"-terpyridine iron(II) complex and compare it with a model bis-terpyridine iron(II) complex by cyclic voltammetry. With the use of different working electrodes, the behavior of these complexes show different electron transfer rates. |
| NASA分類 | Inorganic, Organic and Physical Chemistry |
| 権利 | No Copyright |
| URI | https://repository.exst.jaxa.jp/dspace/handle/a-is/544868 |
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