タイトル | Fischer-Tropsch Cobalt Catalyst Activation and Handling Through Wax Enclosure Methods |
本文(外部サイト) | http://hdl.handle.net/2060/20160011188 |
著者(英) | Yen, Chia H.; Nakley, Leah M.; Klettlinger, Jennifer L. S.; Surgenor, Angela D. |
著者所属(英) | NASA Glenn Research Center |
発行日 | 2016-09-01 |
言語 | eng |
内容記述 | Fischer-Tropsch (F-T) synthesis is considered a gas to liquid process which converts syn-gas, a gaseous mixture of hydrogen and carbon monoxide, into liquids of various hydrocarbon chain length and product distributions. Cobalt based catalysts are used in F-T synthesis and are the focus of this paper. One key concern with handling cobalt based catalysts is that the active form of catalyst is in a reduced state, metallic cobalt, which oxidizes readily in air. In laboratory experiments, the precursor cobalt oxide catalyst is activated in a fixed bed at 350 C then transferred into a continuous stirred tank reactor (CSTR) with inert gas. NASA has developed a process which involves the enclosure of active cobalt catalyst in a wax mold to prevent oxidation during storage and handling. This improved method allows for precise catalyst loading and delivery into a CSTR. Preliminary results indicate similar activity levels in the F-T reaction in comparison to the direct injection method. The work in this paper was supported by the NASA Fundamental Aeronautics Subsonics Fixed Wing Project. |
NASA分類 | Chemistry and Materials (General); Engineering (General) |
レポートNO | NASA/TM-2016-219099 E-19228 GRC-E-DAA-TN5037 |
権利 | Copyright, Distribution as joint owner in the copyright |