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タイトルOxidative Alteration of Ferrous Smectites: A Formation Pathway for Martian Nontronite?
本文(外部サイト)http://hdl.handle.net/2060/20170001688
著者(英)Catalano, J. G.; Agresti, D. G.; Nickerson, R. D.; Rivera-Banuchi, V.; Chemtob, S. M.; Yee, N.; Morris, R. V.; Liu, W.
著者所属(英)NASA Johnson Space Center
発行日2017-03-20
言語eng
内容記述Ferric (Fe3+-bearing) smectites, including nontronite, constitute the majority of hydrous mineral exposures observed on Mars. These smectite exposures are commonly interpreted as weathering products of Martian basaltic crust. However, ferrous (Fe2+-dominated) smectites, not ferric, are the thermo-dynamically predicted products of weathering in anoxic conditions, as predicted for early Mars. Earth was anoxic until the Proterozoic Great Oxidation Event; Mars likely experienced an analogous oxidative evolution to its present oxidized state, but the timing of this evolution is unresolved. We hypothesize that Fe3+-smectites observed by orbital spectroscopy are not the initial products of Noachian-era chemical weathering, but are instead the oxidative products of primary Fe2+-smectites. To test this hypothesis experimentally, we synthesized ferrous smectites and exposed them to Mars-relevant oxidants.
NASA分類Lunar and Planetary Science and Exploration
レポートNOJSC-CN-38832
権利Copyright, Distribution as joint owner in the copyright


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